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Updated: Wed, 26 Feb 2014 16:15:00 GMT | By Tamara Hardingham-Gill
Celebrity couples on the red carpet at the Oscars

Leonardo DiCaprio and Gisele Bündchen

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Leonardo DiCaprio took his then-girlfriend, model Gisele Bündchen, to the 2005 ceremony. The Wolf of Wall Street star was nominated for the Best Actor prize, but lost out to Jamie Foxx. He and Gisele broke up later that year.