The Amazing Spider-Man 2: Shailene Woodley and Andrew Garfield snapped on set
It's Shailene Woodley! Shailene (who starred alongside George Clooney in the Descendants) is set to play Mary-Jane Watson in the movie. In this scene she turns up on a motorbike!
In the comics, Mary Jane (or MJ) is Gwen Stacy's (Emma Stone) friend but things turn sour between the two when Peter grows close with MJ...